jeae journal
EFFECT OF SELECTED PYROLYSIS PARAMETERS ON THE PRODUCTION AND QUALITY OF BIOCHAR AND PYROLIGNEOUS ACID FROM BIOMASS

Abstract

Pyrolysis is an efficient process by which biomass can be utilized to produce biochar and pyroligneous acid which can be used as source of energy for cooking and bio-pesticides, respectively. Current study determined the effect of feedstock moisture content (FMC) (10%, 15% and 20%), pyrolysis residence time (PRT) (90 minutes, 135 minutes, and 180 minutes) and chimney inclination angle (CIA) (30o, 45o and 60o) on the production and quality of biochar and pyroligneous acid (PA). An experimental pyrolysis system was designed, developed, and used. The biochar quality was based on pH, moisture content (MC), volatile matter (VM), ash content (AC) and fixed carbon (FC) while PA was classified using pH and density. The highest production obtained for biochar was 43.66% at FMC = 10%, PRT = 90 min and CIA = 30o and the lowest was 38.74% at FMC = 20% and PRT = 180 min and CIA = 45o while for PA the highest was 31.11% at FMC = 15%, PRT = 90 min and CIA = 30o and the lowest was 25.21% at FMC = 10%, PRT = 180 min and CIA = 60o. The best quality biochar obtained had a pH = 9.10 (FMC = 10%, PRT = 180 min, CIA = 30o), MC = 4.10% (FMC = 10%, PRT = 180 min, CIA = 45o), VM = 21.00% (FMC = 10%, PRT = 180 min, CIA = 30o), AC = 3.60% (FMC = 10%, PRT = 90 min, CIA = 30o) and FC = 70.60% (FMC = 10%, PRT = 180 min, CIA = 30o) while the PA had ρ = 1.05 gcm-3 (FMC = 10%, PRT = 180 min, CIA = 45o) and pH = 2.78 (FMC = 10%, PRT = 180 min, CIA = 30o). The selected pyrolysis parameters except CIA had a significant influence on the biochar production and quality and on the other hand, all the parameters affected the PA production but only PRT had a significant influence on its quality.

https://doi.org/10.37017/jeae-volume8-no2.2022-2
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References

Aguirre, J. L., Baena, J., Martín, M. T., Nozal, L., González, S., Manjón, J. L., & Peinado, M. (2020). Composition, Ageing and Herbicidal Properties of Wood Vinegar Obtained through Fast Biomass Pyrolysis. Energies, 13(10), 2418. https://doi.org/10.3390/en13102418

Ahmad, M., Rajapaksha, A. U., Lim, J. E., Zhang, M., Bolan, N., Mohan, D., Vithanage, M., Lee, S. S., & Ok, Y. S. (2014). Biochar as a sorbent for contaminant management in soil and water: A review. Chemosphere, 99, 19–33.

https://doi.org/10.1016/j.chemosphere.2013.10.0

Ahmad, T., Rafatullah, M., Ghazali, A., Sulaiman, O., Hashim, R., & Ahmad, A. (2010). Removal of Pesticides from Water and Wastewater by Different Adsorbents: A Review. Journal of Environmental Science and Health, Part C, 28(4), 231–271.

https://doi.org/10.1080/10590501.2010.525782

Ahmed, A., Hidayat, S., Abu Bakar, M. S., Azad, A. K., Sukri, R. S., & Phusunti, N. (2021). Thermochemical characterisation of Acacia auriculiformis tree parts via proximate, ultimate,

TGA, DTG, calorific value and FTIR spectroscopy analyses to evaluate their potential as a biofuel resource. Biofuels, 12(1), 9–20.

https://doi.org/10.1080/17597269.2018.1442663

Browning, S., Lawrence, T., Joshi, C., & Seay, J. (2020). Analysis of green pesticide production by valorization of husks from Croton megalocarpus tree nuts. Environmental Progress & Sustainable Energy, 39(4). https://doi.org/10.1002/ep.13312

Chandrasekaran, A., Subbiah, S., Ramachandran, S., Narayanasamy, S., Bartocci, P., & Fantozzi, F. (2019). Natural Draft-Improved Carbonization Retort System for Biocarbon Production from

Prosopis juliflora Biomass. Energy & Fuels,

(11), 11113–11124.

https://doi.org/10.1021/acs.energyfuels.9b02639

Downie, A., Munroe, P., Cowie, A., Van Zwieten, L., & Lau, D. M. S. (2012). Biochar as a Geoengineering Climate Solution: Hazard

Identification and Risk Management. Critical Reviews in Environmental Science and

Technology, 42(3), 225–250.

https://doi.org/10.1080/10643389.2010.507980

Graber, E. R., Frenkel, O., Jaiswal, A. K., & Elad, Y. (2014). How may biochar influence severity of diseases caused by soilborne pathogens? Carbon

Management, 5(2), 169–183.

https://doi.org/10.1080/17583004.2014.913360

Haddad, K., Jeguirim, M., Jellali, S., Thevenin, N., Ruidavets, L., & Limousy, L. (2021). Biochar production from Cypress sawdust and olive mill wastewater: Agronomic approach. Science of The

Total Environment, 752, 141713.

https://doi.org/10.1016/j.scitotenv.2020.141713

Hou, X., Qiu, L., Luo, S., Kang, K., Zhu, M., & Yao, Y. (2018). Chemical constituents and antimicrobial activity of wood vinegars at different pyrolysis temperature ranges obtained from Eucommia ulmoides Olivers branches. RSC Advances, 8(71), 40941–40949.

https://doi.org/10.1039/C8RA07491G

Igalavithana, A. D., Mandal, S., Niazi, N. K., Vithanage,

M., Parikh, S. J., Mukome, F. N. D., Rizwan, M., Oleszczuk, P., Al-Wabel, M., Bolan, N., Tsang, D. C. W., Kim, K.-H., & Ok, Y. S. (2017). Advances and future directions of biochar characterization methods and applications. Critical Reviews in Environmental Science and

Technology, 47(23), 2275–2330. https://doi.org/10.1080/10643389.2017.1421844

Kapoor, L., Bose, D., & Mekala, A. (2020). Biomass pyrolysis in a twin-screw reactor to produce green fuels. Biofuels, 11(1), 101–107.

https://doi.org/10.1080/17597269.2017.1345360

Kizza, R., Banadda, N., Kabenge, I., Seay, J., Willet, S., Kiggundu, N., & Zziwa, A. (2019). Pyrolysis of Wood Residues in a Cylindrical Batch Reactor:

Effect of Operating Parameters on the Quality and Yield of Products. Journal of Sustainable

Development, 12(5), 112.

https://doi.org/10.5539/jsd.v12n5p112

Le Roux, É., Barnabé, S., Godbout, S., Zamboni, I., & Palacios, J. (2020). Production and characterization of two fractions of pyrolysis liquid from agricultural and wood residues. Biomass Conversion and Biorefinery.

https://doi.org/10.1007/s13399-020-01015-2

Lu, X., Jiang, J., He, J., Sun, K., & Sun, Y. (2019). Pyrolysis of Cunninghamia lanceolata Waste to Produce Wood Vinegar and Its Effect on the Seeds Germination and Root Growth of Wheat. 16.

Mahood, H. B., Campbell, A. N., Thorpe, R. B., & Sharif, A. O. (2015). Heat transfer efficiency and capital cost evaluation of a three-phase direct contact heat exchanger for the utilisation of lowgrade energy sources. Energy Conversion and

Management, 106, 101–109.

https://doi.org/10.1016/j.enconman.2015.09.023

Medeiros, L. C. D. de, Pimenta, A. S., Braga, R. M., Carnaval, T. K. de A., Medeiros Neto, P. N., and Melo, D. M. de A. (2019). Effect of Pyrolysis Heating Rate on the Chemical Composition of Wood Vinegar from Eucalyptus Urograndis and Mimosa Tenuiflora. Revista Árvore, 43(4), e430408. https://doi.org/10.1590/1806-

Mythili, R., & Venkatachalam, P. (2015). Product Yield and Characteristics of Char. Energy Sources, Part A: Recovery, Utilization, and Environmental

Effects, 37(24), 2632–2638.

https://doi.org/10.1080/15567036.2012.721862

Oramahi, H. A., & Diba, F. (2013). Maximizing the Production of Liquid Smoke from Bark of Durio by Studying its Potential Compounds. Procedia Environmental Sciences, 17, 60–69.

https://doi.org/10.1016/j.proenv.2013.02.012

Qin, L., Shao, Y., Hou, Z., & Jiang, E. (2020). Effect of temperature on the physicochemical characteristics of pine nut shell pyrolysis products in a screw reactor. Energy Sources, Part A:

Recovery, Utilization, and Environmental Effects,

(22), 2831–2843.

https://doi.org/10.1080/15567036.2019.1618993

Rabiu, Z., and Zakaria, Z. A. (2017). Pyrolignous Acid Production from Palm Kernel Shell Biomass. 4.

Raju, C. A. I., Satya, M., Praveena, U., & Jyothi, K. R.

(2014). Studies On Development Of Fuel

Briquettes Using Locally Avaliable Waste. 4(3),

Ronsse, F., van Hecke, S., Dickinson, D., & Prins, W. (2013). Production and characterization of slow pyrolysis biochar: Influence of feedstock type and pyrolysis conditions. GCB Bioenergy, 5(2), 104–

https://doi.org/10.1111/gcbb.12018

Siriwardena, B. P., Subasinghe, S., Vidanapathirana, N. P., & Dhanushka, T. G. B. (2020). Effects of pyroligneous acids (wood vinegar) produced from different wood species on vegetative growth of eggplant (Solanum melongena L.). 6(1), 5.

Song, W., & Guo, M. (2012). Quality variations of poultry litter biochar generated at different pyrolysis temperatures. Journal of Analytical and Applied

Pyrolysis, 94, 138–145.

https://doi.org/10.1016/j.jaap.2011.11.018

Theapparat, Y., Chandumpai, A., & Faroongsarng, D. (2018). Physicochemistry and Utilization of Wood Vinegar from Carbonization of Tropical

Biomass Waste. In P. Sudarshana, M. NageswaraRao, & J. R. Soneji (Eds.), Tropical Forests—

New Edition. InTech.

https://doi.org/10.5772/intechopen.77380

Thibanyane, N., Agachi, P., & Danha, G. (2019). Effects of biomass/coal copyrolysis parameters on the product yield: A review. Procedia Manufacturing, 35, 477–487.

https://doi.org/10.1016/j.promfg.2019.07.007

Wu, W., Yang, M., Feng, Q., McGrouther, K., Wang, H., Lu, H., & Chen, Y. (2012). Chemical characterization of rice straw-derived biochar for soil amendment. Biomass and Bioenergy, 47, 268–276.

https://doi.org/10.1016/j.biombioe.2012.09.034

Yaashikaa, P. R., Senthil Kumar, P., Varjani, S. J., and Zheng, X., Shi, T., Song, W., Xu, L., & Dong, J. (2020).

Saravanan, A. (2019). Advances in production Biochar of distillers’ grains anaerobic digestion and application of biochar from lignocellulosic residue: Influence of pyrolysis conditions on its feedstocks for remediation of environmental characteristics and ammonium adsorptive pollutants. Bioresource Technology, 292, 122030. optimization. Waste Management & Research, https://doi.org/10.1016/j.biortech.2019.122030 38(1_suppl), 86–97.

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